141229-80-3Relevant academic research and scientific papers
A Novel C=C Bond Cleavage in Hexacarbonyl(hexapentaene)diiron: X-Ray Crystal Structure of a Bis(μ3,η2-allenylidene)-Iron Complex
Iyoda, Masahiko,Kuwatani, Yoshiyuki,Oda, Masaji
, p. 399 - 400 (2007/10/02)
Aryl-substituted hexacarbonyl(hexapentaene)diiron complexes undergo facile intramolecular C=C bond cleavage on treatment with to yield the corresponding bis(μ3,η2-allenylidene)-iron complexes; the X-ray crystal structures of phenyl-substituted bis(μ3,η2-allenylidene)-iron and related allenylidene complexes are determined.
