141232-78-2Relevant academic research and scientific papers
9-BORABICYCLONONANE INDUCED FRAGMENTATION OF 2-AZANORBORNENES: A FORMAL BORA-AZA RETRO ENE REACTION
Gaul, Micheal D.,Fowler, Kerry W.,Grieco, Paul A.
, p. 3099 - 3102 (1993)
N-Substituted 2-azanorbornenes undergo a 9-borabicyclononane induced fragmentation in tetrahydrofuran giving rise to cyclopentenylmethyl amines (cf 3 and 5).
Palladium-catalyzed reduction of an allylic amine: A formal access to both diastereoisomers of cyclopentenyl glycine
Borugeois-Cury,Doan,Gore
, p. 1277 - 1280 (2007/10/02)
The easily accessible bicyclic amines 3 (exo or endo) are regioselectively transformed to the methyl esters of the diastereoisomers (1c or 1d) of N-benzyl cyclopentenylglycine by reaction with hydride donors (mainly NaBH3CN) in the presence of
