141240-19-9

Upstream product

• 144427-53-2 (E)-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol 
• 141240-05-3 (Z)-1,3-di-O-acetyl-2,4-O-benzylidene-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol 
• 144427-55-4 (E)-1,2,3,4-tetra-O-acetyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol 

Downstream Products

• 141240-21-3 2,3,4-Tri-O-acetyl-1-O-tert-butyldimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hexitol 
• 141240-29-1 2,3-Di-O-acetyl-1,4-anhydro-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hexitol 
• 141240-18-8 1,2,3,4-Tetra-O-acetyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hexitol 
• 141240-42-8 2,3,4-Tri-O-acetyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-1-O-methanesulfonyl-D-xylo-hexitol 
• 141240-26-8 5,6-Dideoxy-6-C-(2,4-dichlorophenyl)2,3,4-tri-O-(4-methoxybenzyl)-1-O-tri-phenylmethyl-D-xylo-hexitol 
• 141240-25-7 2,4-Dichloro-1-((3R,4S,5S)-3,4,5-tris-benzyloxy-6-trityloxy-hexyl)-benzene 
• 141240-24-6 Acetic acid (1S,2S,3R)-2,3-diacetoxy-5-(2,4-dichloro-phenyl)-1-trityloxymethyl-pentyl ester 
• 141240-32-6 Toluene-4-sulfonic acid (2S,3S,4R)-2,3,4-tris-benzyloxy-6-(2,4-dichloro-phenyl)-hexyl ester 
• 141267-47-2 Sodium 2,6,7-trideoxy-7-C-(2,4-dichlorophenyl)-D-xylo-heptonate 
• 141240-39-3 2,6,7-Trideoxy-7-C-(2,4-dichlorophenyl)-3,4,5-tri-O-(4-methoxybenzyl)-D-xylo-heptonamide 
• 141240-41-7 2,6,7-Trideoxy-7-C-(2,4-dichlorophenyl)-3,4,5-tri-O-(4-methoxybenzyl)-D-xylo-heptonitrile 
• 141240-33-7 1-S-Benzoyl-2,3,4-tri-O-benzyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-1-thio-D-xylo-hexitol 
• 141240-31-5 2,3,4-Tri-O-benzyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-1-O-methanesulfonyl-D-xylo-hexitol 
• 141240-36-0 5,6-Dideoxy-6-C-(2,4-dichlorophenyl)-2,3,4-tri-O-(4-methoxybenzyl)-D-xylo-hexitol 

Relevant academic research and scientific papers

Rearrangement of unsaturated 2,4-O-benzylidenehexitol derivatives into C-glycosylbenzene derivatives

Acetolysis of (Z)-1,3-di-O-acetyl-2,4-O-benzylidene-6-C-(2,4-dichlorophenyl)-D-xylo -hex-5-enitol (3) afforded (E)-1,2,3,4-tetra-O-acetyl-6-C-(2,4-dichlorphenyl)-D-xylo-hex-5- enitol and 2-C-[(R)-acetoxy(2,4-dichlorophenyl)methyl]- 3,4,6-tri-O-acetyl-2-de

Synthesis of 2,6,7-trideoxy-7-C-(2,4-dichlorophenyl)-D-xylo-heptonic acid and 6-(2,4-dichlorophenyl)-D-xylo-2,3,4-tri-hydroxyhexanesulfonic acid

2,4-0-Benzylidene-L-xylose was converted via a Wittig reaction into Z-2,4-0-benzylidene-5,6-di-deoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex- 5-enitol (17), which, on hydrogenation, gave 5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hexitol (33). tert-Butyldime