141249-90-3

Upstream product

• 125219-21-8 benzyl 2,3,6-tri-O-benzyl-4-deoxy-4-C-(methylene)-α-D-xylo-4-hexopyranoside 
• 141249-89-0 benzyl 2,3,6-tri-O-benzyl-4-C-(hydroxymethyl)-α-D-glucopyranoside 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 141249-91-4 1,2,3,6-tetra-O-acetyl-4-C-(tosyloxymethyl)-D-glucopyranose 

Relevant academic research and scientific papers

Synthesis of 4-Epoxy-4-C-methyleneglycosylceramides, Potential Glycosyltransferase Inhibitors

D-Glucose was transformed into the 4-deoxy-4-C-methylene derivative 1.Dihydroxylation of 1 and then selective O-tosylation afforded 4-C-(tosyloxymethyl)glucoside 3.Subsequent hydrogenolytic O-debenzylation, selective O-acetylation, treatment with a base,