141258-49-3

Upstream product

• 64818-36-6 5-hexenyl methanesulfonate 
• 141258-39-1 (13R)-methyl-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-13-(2-tetrahydropyranylpxy)-4-octadecynoate 
• 141258-40-4 (13R)-methyl-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-13-hydroxy-4-octadecynoate 
• 141258-44-8 ((S)-1-Naphthalen-1-yl-ethyl)-carbamic acid (R)-1-pentyl-oct-7-enyl ester 
• 141258-38-0 (13R)-methyl-7-hydroxy-13-(2-tetrahydropyranyloxy)-4-octadecynoate 
• 141258-46-0 (8R)-8-(2-tetrahydropyranyloxy)-1-tridecene 
• 141258-37-9 (8R)-8-(2-tetrahydropyranyloxy)tridecane-1,2-oxide 
• 141317-60-4 (6R)-12-tridecen-6-ol 
• 141258-43-7 (+/-)-12-tridecen-6-ol 
• 2695-47-8 6-Bromo-1-hexene 
• 821-41-0 5-Hexen-1-ol 
• 592-76-7 1-Heptene 
• 5063-65-0 1,2-epoxyheptane 
• 141258-42-6 (13R)-8-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-13-pentyloxacyclotetradec-5-yn-2-one 

Downstream Products

• 88936-02-1 (-)-gloeosporone 

Relevant academic research and scientific papers

Synthesis of a germination self-inhibitor, (-)-gloeosporone, and related compounds and evaluation of their activities

Synthesis of (-)-gloeosporone (1a), isolated from spores of Colletotrichum gloeosporioides as a self-inhibitor for germination, and its three diastereomers was accomplished starting from (S)- and (R)-1-tridecen-8-ol obtained from their (S)-naphthyl ethylcarbamates (8a and 8b), both of which were isolated from the mixture of diastereoisomers derived from racemic 1-tridecen-8-ol (7) and the Pirkle reagent. Biological testing of the compounds showed weak self-inhibitor activity toward germination of the spores.