14127-18-5Relevant academic research and scientific papers
Synthesis and structure of Co(III) coordination compounds [Co(DH) 2(Anil)2][BF4] and [Co(DH)2(Py) 2][BF4]
Malinovskii,Coropchanu,Bologa,Bel'skii
, p. 346 - 351 (2002)
The complex compounds [Co(DH)2(Anil)2][BF 4] and [Co(DH)2(Py)2][BF4] were synthesized from Co(BF4)2·6H2O-DH 2-A-alcohol-water systems (DH2 is dimethylglyoxim and A is pyridine (Py) or aniline (Anil)), and their crystal structures were determined using X-ray diffraction analysis. In octahedral Co(III) complexes, two dimethylglyoxime radicals lie in the equatorial plane and are joined via the intramolecular hydrogen bond O-H...O. The complexes with pyridine and aniline have similar configurations but different crystal structures.
