14129-98-7

Usage

Uses

Used in Agricultural Chemicals Industry:
Phosphorothioic trimorpholide is used as a building block for the production of pesticides and insecticides, contributing to the development of effective agricultural chemicals for pest control and crop protection.
Used in Pharmaceutical Industry:
In the pharmaceutical sector, PHOSPHOROTHIOICTRIMORPHOLIDE serves as a precursor for the synthesis of certain drug molecules, playing a crucial role in the development of new medications and therapies.

InChI:InChI=1/C12H24N3O3PS/c20-19(13-1-7-16-8-2-13,14-3-9-17-10-4-14)15-5-11-18-12-6-15/h1-12H2

Upstream product

• 5815-61-2 tris(morpholino)phosphine 
• 110-91-8 morpholine 

Relevant academic research and scientific papers

Studies on electrochemical and coordination behaviour of phosphiniminocyclotrithiazenes

Electrochemical (polarographic, cyclic voltammetric, and coulometric) and coordination behaviour of several symmetrically and unsymmetrically substituted phosphiniminocyclotrithiazenes have been studied. Polarograms of R3PN-S3N3 R = C6H5, p-ClC6H4, p-H3CC6H4, and (OC4H8N)), Ph2OC4H8N)PN-S3N3, and Ph(OC4H8N)2PN-S3N3 give two cathodic waves. Cyclic voltammograms of Ph3PN-S3N3 (1) and (OC4H8N)3PN-S3N3 (2) reveal nearly the same oxidation peak potential but different reduction potentials. Controlled potential electrolysis of 1 and 2 at +0.6 V indicates exocyclic cleavage and ring degradation. Cathodic reduction behaviour of Ph3PN-S3N3 suggests the possibility for the) formation of 1,5-(Ph)3(PN)2S4N4 under electrochemical conditions. Reaction of nickel chloride hexahydrate with heterocycle 1 in 1:2 molar ratio in acetonitrile affords the complex, ([NiS2N2H2] (A) (90% yield) and [Ph3PNH2]Cl salt as products. Analogous reactions with other ligands of this type (two symmetrical (sym.) and three unsymmetrical (unsym.)) except 2 also give A, while ligand 2 reacts with anhyd NiCl2 in an equimolar ratio to afford a dark green, square-planar complex ((OC4H8N)3(PN-S3(N·NiCl 2 (B)) whose ESCA results assist in providing its coordination details. The study reveals a high tendency of these heterocycles to different types of ring cleavage.

Studies on iodination reactions of phosphiniminocyclotrithiazenes

Iodination reactions of various phosphiniminocyclotrithiazenes [R 3PNS3N3; R = (i) phenyl-, (ii) morpholino-, and (iii) p-chlorophenyl-] have been studied under different experimental conditions. Iodination of Ph3PNS3N3 yields interesting products such as [(Ph3PN)2S3N 3]I3, ((Ph3PN)3S)2I 4, (Ph3PNH2)I3, ((Ph 3PSI2)2I2, and [(Ph 3PN)3SO]2I6 depending on the experimental conditions. All the products have been isolated and characterized by the spectroscopic and analytical techniques. Copyright Taylor & Francis Group, LLC.