14129-98-7

Basic information

• Product Name: PHOSPHOROTHIOICTRIMORPHOLIDE
• Synonyms: PHOSPHOROTHIOICTRIMORPHOLIDE;Phosphorothioic acid trimorpholide;Trimorpholinophosphine sulfide;4,4',4''-phosphorothioyltrimorpholine
• CAS NO: 14129-98-7
• Molecular Formula: C12H24 N3 O3 P S
• Molecular Weight: 321.42
• Mol File: 14129-98-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 455.7°Cat760mmHg
• Flash Point: 229.4°C
• Appearance: /
• Density: 1.32g/cm³
• Vapor Pressure: 1.73E-08mmHg at 25°C
• Refractive Index: 1.591
• Water Solubility: 3.21g/L(25 oC)
• CAS DataBase Reference: PHOSPHOROTHIOICTRIMORPHOLIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PHOSPHOROTHIOICTRIMORPHOLIDE(14129-98-7)
• EPA Substance Registry System: PHOSPHOROTHIOICTRIMORPHOLIDE(14129-98-7)

Safety Data

• Hazardous Substances Data: 14129-98-7(Hazardous Substances Data)

Usage

General Description

Phosphorothioic trimorpholide is a chemical compound consisting of phosphorus, sulfur, oxygen, and carbon atoms, with the molecular formula C6H15O4PS. It is a phosphorothioate ester and is commonly used as a chemical intermediate in the synthesis of various organic compounds. Phosphorothioic trimorpholide is a colorless to pale yellow liquid with a characteristic odor and is soluble in organic solvents. It is known for its reactivity and is used as a building block in the production of pesticides, insecticides, and other agricultural chemicals. It is also used in the pharmaceutical industry as a precursor for the synthesis of certain drug molecules. The compound is considered to be hazardous and should be handled with care due to its potential toxicity and reactivity.

InChI:InChI=1/C12H24N3O3PS/c20-19(13-1-7-16-8-2-13,14-3-9-17-10-4-14)15-5-11-18-12-6-15/h1-12H2

Upstream product

• 110-91-8 morpholine 
• 5815-61-2 tris(morpholino)phosphine 

Relevant articles and documents

Studies on electrochemical and coordination behaviour of phosphiniminocyclotrithiazenes

Electrochemical (polarographic, cyclic voltammetric, and coulometric) and coordination behaviour of several symmetrically and unsymmetrically substituted phosphiniminocyclotrithiazenes have been studied. Polarograms of R3PN-S3N3 R = C6H5, p-ClC6H4, p-H3CC6H4, and (OC4H8N)), Ph2OC4H8N)PN-S3N3, and Ph(OC4H8N)2PN-S3N3 give two cathodic waves. Cyclic voltammograms of Ph3PN-S3N3 (1) and (OC4H8N)3PN-S3N3 (2) reveal nearly the same oxidation peak potential but different reduction potentials. Controlled potential electrolysis of 1 and 2 at +0.6 V indicates exocyclic cleavage and ring degradation. Cathodic reduction behaviour of Ph3PN-S3N3 suggests the possibility for the) formation of 1,5-(Ph)3(PN)2S4N4 under electrochemical conditions. Reaction of nickel chloride hexahydrate with heterocycle 1 in 1:2 molar ratio in acetonitrile affords the complex, ([NiS2N2H2] (A) (90% yield) and [Ph3PNH2]Cl salt as products. Analogous reactions with other ligands of this type (two symmetrical (sym.) and three unsymmetrical (unsym.)) except 2 also give A, while ligand 2 reacts with anhyd NiCl2 in an equimolar ratio to afford a dark green, square-planar complex ((OC4H8N)3(PN-S3(N·NiCl 2 (B)) whose ESCA results assist in providing its coordination details. The study reveals a high tendency of these heterocycles to different types of ring cleavage.