1412902-47-6Relevant academic research and scientific papers
Enantioselective Synthesis of 4,4′-Biaryl-BINOLs from Arynes and β-Diketones
Okuma, Kentaro,Horigami, Kenta,Nagahora, Noriyoshi,Shioji, Kosei
, p. 2937 - 2944 (2015)
The reaction of 2-(trimethylsilyl)phenyl triflate with aroylacetones in the presence of CsF gave the corresponding 4-aryl-2-naphthols. Substituted triflates also reacted with aroylacetones to afford 4-aryl-2-naphthols regioselectively. The enantioselectiv
Tandem carbon-carbon bond insertion and intramolecular aldol reaction of benzyne with aroylacetones: Novel formation of 4,4′-disubstituted 1,1′-binaphthols
Okuma, Kentaro,Itoyama, Ryoichi,Sou, Ayumi,Nagahora, Noriyoshi,Shioj, Kosei
supporting information, p. 11145 - 11147 (2013/01/15)
An efficient route to 4-aryl-2-naphthols from arynes and aroylacetones was developed by carbon-carbon bond insertion followed by an intramolecular aldol reaction and dehydration. Benzyne derived from 2-(trimethylsilyl)phenyl triflate reacted with benzoyla
