1412912-77-6

Basic information

• Product Name: C₃₃H₂₆BN
• CAS NO: 1412912-77-6
• Molecular Weight: 447.387
• Mol File: 1412912-77-6.mol

Chemical Properties

• CAS DataBase Reference: C₃₃H₂₆BN(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₃H₂₆BN(1412912-77-6)
• EPA Substance Registry System: C₃₃H₂₆BN(1412912-77-6)

Safety Data

• Hazardous Substances Data: 1412912-77-6(Hazardous Substances Data)

Upstream product

• 31785-72-5 1-methyl-2-pyrrolyllithium 
• 62707-11-3 1-chloro-2,3,4,5-tetraphenylborole 

Downstream Products

• 1412912-73-2 1-(N-methylpyrrol-2-yl)-2,3,4,5-tetraphenylborole dimethylaminopyridine 

Relevant articles and documents

1-Heteroaromatic-substituted tetraphenylboroles: π-π Interactions between aromatic and antiaromatic rings through a B-C bond

A series of 2,3,4,5-tetraphenylboroles substituted with different aromatic heterocycles (thiophene, furan, pyrrole, and dithiophene) in the 1-position were synthesized and characterized by means of NMR, elemental analysis, and X-ray crystallography. In contrast to known 2,3,4,5-tetraphenylboroles, X-ray diffraction revealed a nearly coplanar arrangement of the aromatic heterocycles and the antiaromatic borole scaffold as a result of π-conjugation, which could be substantiated by DFT calculations. Furthermore, the 2,2′-dithiophene-bridged bisborole (14) exhibits a large bathochromic shift in the absorption spectrum, demonstrating the exceptional Lewis acidity of the nonannulated borolyl moiety.