141355-03-5Relevant articles and documents
Enantioselective reduction of benzoyl derivatives of ferrocene and ruthenocene: optically active carbinols and carbenium ions
Nefedova, Marina N.,Mamedyarova, Irina A.,Petrovski, Pavel P.,Sokolov, Viatcheslav I.
, p. 125 - 130 (1992)
Mono- and 1,1'-disubstituted metallocenes, XC5H4MC5H4Y, M = Fe, Ru, X = H, Y = COPh, or X = Y = COPh, have been reduced using the LiAlH4-Chirald complex to afford the corresponding carbinols and diols enantiomerically enriched.Optical yield was 53percent