141361-97-9Relevant academic research and scientific papers
Copper-catalyzed carboxylation of alkylboranes with carbon dioxide: Formal reductive carboxylation of terminal alkenes
Ohmiya, Hirohisa,Tanabe, Masahito,Sawamura, Masaya
supporting information; experimental part, p. 1086 - 1088 (2011/04/23)
Carboxylation of alkylboron compounds (alkyl-9-BBN) with CO2 proceeded in the presence of catalytic amounts of CuOAc/1,10-phenanthroline and a stoichiometric amount of KOtBu. The alkylboranes are easily and widely available through the alkene hydroboration, and thus the overall process represents a reductive carboxylation of alkenes with CO2. The broad functional group compatibility and the inexpensiveness of the Cu/1,10-phenathoroline catalyst system are attractive features of this protocol.(Figure Presented)
