1413935-02-0

Basic information

• Product Name: 5-(benzyloxy)-3-methylpent-1-en-3-yl methyl carbonate
• Synonyms: 5-(benzyloxy)-3-methylpent-1-en-3-yl methyl carbonate
• CAS NO: 1413935-02-0
• Molecular Weight: 264.321
• Mol File: 1413935-02-0.mol

Chemical Properties

• CAS DataBase Reference: 5-(benzyloxy)-3-methylpent-1-en-3-yl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(benzyloxy)-3-methylpent-1-en-3-yl methyl carbonate(1413935-02-0)
• EPA Substance Registry System: 5-(benzyloxy)-3-methylpent-1-en-3-yl methyl carbonate(1413935-02-0)

Safety Data

• Hazardous Substances Data: 1413935-02-0(Hazardous Substances Data)

Upstream product

• 19758-82-8 (+/-)-5-Benzyloxy-3-methyl-penten-⁽¹⁾-ol-⁽³⁾ 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1413934-93-6 2-[2-(benzyloxy)ethyl]-2-methyl-1-phenylbut-3-en-1-one 

Relevant articles and documents

Regioselective and Stereospecific Rhodium-Catalyzed Allylic Cyanomethylation with an Acetonitrile Equivalent: Construction of Acyclic β-Quaternary Stereogenic Nitriles

A highly regioselective and stereospecific rhodium-catalyzed cyanomethylation of tertiary allylic carbonates for the construction of acyclic β-quaternary stereogenic nitriles is described. This protocol represents the first example of a metal-catalyzed al

Rhodium-catalyzed allylic substitution with an acyl anion equivalent: Stereospecific construction of acyclic quaternary carbon stereogenic centers

A highly regio- and stereospecific rhodium-catalyzed allylic alkylation of tertiary allylic alcohol derivatives with a cyanohydrin pronucleophile is described. This direct and operationally simple protocol provides a fundamentally novel approach toward the synthesis of α-quaternary substituted ketones and circumvents many of the inherent problems associated with conventional enolate alkylation reactions. The stereospecific variant of this reaction provides the enantiomerically enriched α-quaternary substituted allylic aryl ketone, which is a particularly challenging intermediate for more conventional enolate-based strategies.