141434-71-1

Basic information

• Product Name: 1,5-ANHYDRO-L-GLUCITOL
• Synonyms: 1,5-ANHYDRO-L-GLUCITOL
• CAS NO: 141434-71-1
• Molecular Formula: C₆H₁₂O₅
• Molecular Weight: 164.156
• Mol File: 141434-71-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,5-ANHYDRO-L-GLUCITOL(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-ANHYDRO-L-GLUCITOL(141434-71-1)
• EPA Substance Registry System: 1,5-ANHYDRO-L-GLUCITOL(141434-71-1)

Safety Data

• Hazardous Substances Data: 141434-71-1(Hazardous Substances Data)

Usage

Type

Naturally occurring organic compound

Source

Derived from cellulose during biomass burning and pyrolysis

Occurrence

Commonly found in aerosols and atmospheric particles resulting from the combustion of biomass, such as wood and grass

Use

Identified as a marker for biomass burning and used as a tracer for evaluating the impact of biomass burning on air quality and climate change

Significance

Has been the subject of numerous studies to understand its role in atmospheric chemistry and its potential health implications.

Upstream product

• 84109-50-2 (2R,3R,4S,5R)-3,4,5-Trihydroxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 59-23-4 D-Galactose 
• 50-70-4 D-sorbitol 
• 219510-83-5 (2R,3R,4S,5R)-3,4,5-Triacetoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 20204-84-6 (β-D-Xylopyranosyl)nitromethane 
• 66966-07-2 α/β‐L‐glucopyranosyl‐1,2,3,4,5‐pentaacetate 
• 67337-79-5 2,3,4,6-tetra-O-acetyl-α-L-glucopyranosyl bromide 
• 912847-92-8 tetra-O-acetyl-1,5-anhydro-L-glucitol 

Downstream Products

• 912847-99-5 2-((2,3,4-tri-O-benzyl-β-D-xylopyranosyl)methyl)naphthalene 
• 912847-94-0 1,5-anhydro-2,3,4-tri-O-benzyl-L-glucitol 
• 912847-95-1 2,6-anhydro-3,4,5-tri-O-benzyl-D-glucose 
• 912847-93-9 1,5-anhydro-2,3,4,6-tetra-O-benzyl-L-glucitol 

Relevant articles and documents

Syntheses of 2,6-anhydroaldonic acids from the corresponding anhydrodeoxynitroalditols (glycopyranosylnitromethanes) and their conversion into methyl esters, amides, and alditols

2,6-Anhydroaldonic acids were obtained by oxidation of the corresponding anhydrodeoxynitroalditols (glycopyranosylnitromethanes) with hydrogen peroxide in alkaline solution. Purification was achieved via the methyl anhydroaldonates. The syntheses of five 2,6-anhydrohexonic and eight 2,6-anhydroheptonic acids were accomplished in yields of 44-81%. All corresponding unprotected and acetylated methyl 2,6-anhydroaldonates were characterised. Ammonolysis of the former afforded the corresponding amides in quantitative yields; reduction with sodium borohydride gave the analogous anhydroalditols. Copyright (C) 1998 Elsevier Science Ltd.

Synthesis of aromatic C-xylosides by position inversion of glucose

Two formally C-xylosylated analogs to 2-naphthyl β-d-xylopyranoside, which is known to initiate priming of glucosaminoglycan chains, were synthesized by a position inversion of glucose (i.e., position 1 becomes position 5). The d-C-xyloside showed priming, while the l-C-xyloside did not initiate priming.