1414852-48-4Relevant academic research and scientific papers
Formyl MIDA Boronate: C1 Building Block Enables Straightforward Access to α-Functionalized Organoboron Derivatives
Grygorenko, Oleksandr O.,Ivon, Yevhen M.,Kuchkovska, Yuliya O.,Mazurenko, Ivan V.,Voitenko, Zoya V.
, p. 18016 - 18022 (2020/08/19)
Formyl MIDA boronate has been known to be an elusive type of acylboronate that has not been obtained to date. In this work, an approach to the one-pot preparation and chemical transformations of formyl MIDA boronate were developed to provide new types of
Oxidative geminal functionalization of organoboron compounds
He, Zhi,Trinchera, Piera,Adachi, Shinya,St. Denis, Jeffrey D.,Yudin, Andrei K.
, p. 11092 - 11096 (2013/01/15)
Excellent tolerance: Stable acylboronates equipped with N-methyliminodiacetyl (MIDA) boryl groups ([B]) were prepared by using a sequence of oxidative manipulations at the boron-bound carbon center (green in scheme). Chemoselective transformations of these acylated organoboron building blocks yielded a range of multifunctionalized boron derivatives and supplied access to valuable borylated heterocycles (see scheme). Copyright
