1414852-59-7Relevant academic research and scientific papers
Synthesis of Acylborons by Ozonolysis of Alkenylboronates: Preparation of an Enantioenriched Amino Acid Acylboronate
Taguchi, Jumpei,Ikeda, Toshiki,Takahashi, Rina,Sasaki, Ikuo,Ogasawara, Yasushi,Dairi, Tohru,Kato, Naoya,Yamamoto, Yasunori,Bode, Jeffrey W.,Ito, Hajime
, p. 13847 - 13851 (2017/10/12)
A concise synthesis of acylborons was achieved by ozonolysis of alkenyl MIDA (N-methyliminodiacetic acid) boronates. This reaction exhibits excellent functional-group tolerance and is applicable to various acyl MIDA boronates and potassium acyltriflurobor
Oxidative geminal functionalization of organoboron compounds
He, Zhi,Trinchera, Piera,Adachi, Shinya,St. Denis, Jeffrey D.,Yudin, Andrei K.
, p. 11092 - 11096 (2013/01/15)
Excellent tolerance: Stable acylboronates equipped with N-methyliminodiacetyl (MIDA) boryl groups ([B]) were prepared by using a sequence of oxidative manipulations at the boron-bound carbon center (green in scheme). Chemoselective transformations of these acylated organoboron building blocks yielded a range of multifunctionalized boron derivatives and supplied access to valuable borylated heterocycles (see scheme). Copyright
