1415032-72-2

Basic information

• Product Name: (E)-dimethyl 1-diazo-5-(methoxyimino)-2-oxo-5-phenylpentylphosphonate
• Synonyms: (E)-dimethyl 1-diazo-5-(methoxyimino)-2-oxo-5-phenylpentylphosphonate
• CAS NO: 1415032-72-2
• Molecular Weight: 339.288
• Mol File: 1415032-72-2.mol

Chemical Properties

• CAS DataBase Reference: (E)-dimethyl 1-diazo-5-(methoxyimino)-2-oxo-5-phenylpentylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-dimethyl 1-diazo-5-(methoxyimino)-2-oxo-5-phenylpentylphosphonate(1415032-72-2)
• EPA Substance Registry System: (E)-dimethyl 1-diazo-5-(methoxyimino)-2-oxo-5-phenylpentylphosphonate(1415032-72-2)

Safety Data

• Hazardous Substances Data: 1415032-72-2(Hazardous Substances Data)

Upstream product

• 1415033-03-2 (E)-dimethyl 5-(methoxyimino)-2-oxo-5-phenylpentylphosphonate 

Downstream Products

• 1415032-86-8 dimethyl (3-hydroxy-6-phenylpyridin-2-yl)phosphonate 

Relevant articles and documents

Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines

Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N-O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5-10 minutes in good to excellent yields.