141508-36-3Relevant academic research and scientific papers
Formal Total Synthesis of (-)-Dendrobine Using Zirconium Promoted Cyclization. Determination of the Absolute Configuration of the Intermediary Tricyclic Ketone
Mori, Miwako,Saitoh, Fumihiko,Uesaka, Noriaki,Shibasaki, Masakatsu
, p. 213 - 216 (1993)
The optical purity of (-)-dendrobine synthesized using zirconium promoted cyclization was improved and the absolute configuration of the intermediary tricyclic ketone was determined using the improved Mosher's method developed by Kusumi.
Formal total synthesis of (-)-dendrobine using zirconium-promoted reductive cyclization
Uesaka,Saitoh,Mori,Shibasaki,Okamura,Date
, p. 5633 - 5642 (2007/10/02)
The alkaloid (-)-dendrobine was synthesized from (+)-calvone by a short sequence using zirconium-promoted reductive cyclization. The absolute configuration of a synthetic intermediate was determined by an improved version of Mosher's method.
