1415100-64-9Relevant academic research and scientific papers
Anionic iron complexes with a bond between an ate-type pentacoordinated germanium and an iron atom
Kano, Naokazu,Yoshinari, Naohito,Shibata, Yusuke,Miyachi, Mariko,Kawashima, Takayuki,Enomoto, Masaya,Okazawa, Atsushi,Kojima, Norimichi,Guo, Jing-Dong,Nagase, Shigeru
, p. 8059 - 8062 (2012)
The first stable anionic iron(0) complexes bearing an ate-type pentacoordinated germanium(IV) ligand were synthesized. The X-ray crystallographic analysis shows trigonal-bipyramidal and piano-stool geometries of germanium and iron, respectively. The complexes have moderately electron-rich iron centers and polar Ge-Fe bonds which can be cleaved by oxidation.
