1415227-07-4

Upstream product

• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 1415227-03-0 C₁₅H₁₃AgIN₃ 
• 128706-72-9 [Ru(p-cymene)Cl₂]2 
• 1263862-39-0 3-methyl-1,4-diphenyl-1,2,3-triazolium tetrafluoroborate 

Relevant academic research and scientific papers

Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C-H bond activation.

Wingtip substituents tailor the catalytic activity of ruthenium triazolylidene complexes in base-free alcohol oxidation

A series of RuII (η6-arene) complexes with 1,2,3-triazolylidene ligands comprising different aryl and alkyl wingtip groups have been prepared and characterized by NMR spectroscopy, microanalysis, and in one case by X-ray diffraction.

Regioselective electrophilic C-H bond activation in triazolylidene metal complexes containing a N-bound phenyl substituent

Transmetalation of a 1,4-diphenyl-substituted 1,2,3-triazolylidene silver complex with an electrophilic metal center, e.g., RuII, Ir III, or RhIII, induces spontaneous and chemoselective cyclometalation involving C-H bond activation of the N-bound phenyl group exclusively. Less electrophilic metals such as IrI, RhI, and PtII yield a monodentate triazolylidene complex, while cyclometalation with borderline cases (PdII) or the activation of the C-bound phenyl ring requires acetate as a promoter.