1415246-59-1

Basic information

• Product Name: [Ni(dioxime)2]
• Synonyms: [Ni(dioxime)2]
• CAS NO: 1415246-59-1
• Molecular Weight: 441.109
• Mol File: 1415246-59-1.mol

Chemical Properties

• CAS DataBase Reference: [Ni(dioxime)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(dioxime)2](1415246-59-1)
• EPA Substance Registry System: [Ni(dioxime)2](1415246-59-1)

Safety Data

• Hazardous Substances Data: 1415246-59-1(Hazardous Substances Data)

Upstream product

• 937-30-4 4-ethylacetophenone 

Relevant articles and documents

Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst

Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by 1H and 13C NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)2] complex (2). Then, the intramolecular O-H?O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)2Cu2(N-N) 2](ClO4)2 oxime complexes (3-7) where N-N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2, 2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime) 2] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes.