1415486-41-7Relevant academic research and scientific papers
A convenient synthesis of anthranilic acids by Pd-catalyzed direct intermolecular ortho-C-H amidation of benzoic acids
Ng, Ka-Ho,Ng, Fo-Ning,Yu, Wing-Yiu
supporting information, p. 11680 - 11682,3 (2012/12/12)
An efficient method for synthesis of anthranilic acids by Pd-catalyzed ortho-C-H amidation of benzoic acids is disclosed. The amidation is proposed to proceed by carboxylate-assisted ortho-C-H palladation to form an arylpalladium(ii) complex, followed by nitrene insertion to the Pd-C bond.
