141563-16-8

Basic information

• Product Name: (Z)-N¹-acetyl-N³-(2-amino-1,2-dicyanovinyl)formamidrazone
• CAS NO: 141563-16-8
• Molecular Weight: 192.18
• Mol File: 141563-16-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-N¹-acetyl-N³-(2-amino-1,2-dicyanovinyl)formamidrazone(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-N¹-acetyl-N³-(2-amino-1,2-dicyanovinyl)formamidrazone(141563-16-8)
• EPA Substance Registry System: (Z)-N¹-acetyl-N³-(2-amino-1,2-dicyanovinyl)formamidrazone(141563-16-8)

Safety Data

• Hazardous Substances Data: 141563-16-8(Hazardous Substances Data)

Upstream product

• 129694-52-6 ethyl (Z)-N-(2-amino-1,2-dicyanovinyl)formamidate 
• 108-24-7 acetic anhydride 
• 141563-05-5 (Z)-N³-(2-amino-1,2-dicyanovinyl)formamidrazone 

Relevant articles and documents

(Z)-N3-(2-Amino-1,2-dicyanovinyl)formamidrazone: a Precursor in the Synthesis of 1,5-Diaminoimidazoles and 6-Carbamoyl-1,2-dihydropurines

The reaction of ethyl (Z)-N-(2-amino-1,2-dicyanovinyl)formimidate with hydrazine monohydrate leads to (Z)-N3-(2-amino-1,2-dicyanovinyl)formamidrazone in almost quantitative yield.This compound proved to be an important starting material for the synthesis of the corresponding N1-isopropylidene- and N1-acetyl-formamidrazones.The amidrazones prepared promptly cyclize in the presence of base to give a 1,5-diamino-4-cyanoimidazole or a 1,5-diamino-4-(cyanoformimidoyl)imidazole, depending on the reaction conditions and mainly on the nature of the base used to induce cyclization. 1,5-Diamino-4-(cyanoformimidoyl)imidazole was treated with carbonyl compounds and the 1,2-dihydropurines thus isolated indicated that the amino group in position 5 is more reactive than that in position 1.