141606-35-1Relevant articles and documents
Nanoporous palladium catalyzed one-pot synthesis N-alkyl amines by hydrogen transfer reaction under mild conditions
Cao, Xiaoqun,Cao, Yang,Hou, Chao,Li, Zhiwen
, (2020/08/06)
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Selective reductive amination of aldehydes from nitro compounds catalyzed by molybdenum sulfide clusters
Pedrajas,Sorribes,Junge,Beller,Llusar
supporting information, p. 3764 - 3768 (2017/08/21)
Secondary amines are selectively obtained from low value starting materials using hydrogen and a non-noble metal-based catalyst. The reductive amination of aldehydes from nitroarenes or nitroalkanes is efficiently catalyzed by a well-defined diamino molybdenum sulfide cluster in a one-pot homogeneous reaction. The integrity of the molecular cluster catalyst is preserved along the process.
Synthesis of substituted oxindoles from α-chloroacetanilides via palladium-catalyzed C - H functionalization
Hennessy, Edward J.,Buchwald, Stephen L.
, p. 12084 - 12085 (2007/10/03)
A novel method for the synthesis of oxindoles is described. In the presence of catalytic palladium acetate and 2-(di-tert-butylphosphino)biphenyl, α-chloroacetanilides are converted to oxindoles in good to excellent yields with high functional group compatibility using triethylamine as a stoichiometric base. The cyclization is highly regioselective, obviating the need for prefunctionalized arenes. Plausible mechanistic pathways for the reaction are discussed. Copyright
