1416368-06-3

Basic information

• Product Name: N,N'-Bis(2,6-bis(diphenylMethyl)-4-Methoxyphenyl)iMidazol-2-ylidene, Min. 98% IPr*OMe
• Synonyms: N,N'-Bis(2,6-bis(diphenylMethyl)-4-Methoxyphenyl)iMidazol-2-ylidene, Min. 98% IPr*OMe;IPr*Ome;N,N'-Bis(2,6-bis(diphenylmethyl)-4-methoxyphenyl)imidazol-2-ylidene
• CAS NO: 1416368-06-3
• Molecular Formula: C₆₉H₅₆N₂O₂
• Molecular Weight: 945.19514
• Mol File: 1416368-06-3.mol
• Article Data: 1

Chemical Properties

• Appearance: white/Powder
• Sensitive: air sensitive, moisture sensitiv
• CAS DataBase Reference: N,N'-Bis(2,6-bis(diphenylMethyl)-4-Methoxyphenyl)iMidazol-2-ylidene, Min. 98% IPr*OMe(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-Bis(2,6-bis(diphenylMethyl)-4-Methoxyphenyl)iMidazol-2-ylidene, Min. 98% IPr*OMe(1416368-06-3)
• EPA Substance Registry System: N,N'-Bis(2,6-bis(diphenylMethyl)-4-Methoxyphenyl)iMidazol-2-ylidene, Min. 98% IPr*OMe(1416368-06-3)

Safety Data

• Hazardous Substances Data: 1416368-06-3(Hazardous Substances Data)

Usage

Reactions

Ligand for allene hydrosilylations with nickel

Upstream product

• 1416368-01-8 2,6-bis(diphenylmethyl)-4-methoxy-benzenamine 
• 1416368-02-9 N,N’-bis(4-methoxy-2,6-(diphenylmethyl)phenyl)ethane-1,2-diimine 
• 104-94-9 4-methoxy-aniline 
• 91-01-0 1,1-Diphenylmethanol 

Relevant articles and documents

[Pd(IPr*OMe)(acac)Cl]: Tuning the N-heterocyclic carbene in catalytic C-N bond formation

A new N-heterocyclic ligand IPr*OMe [N,N′-bis(2,6- bis(diphenylmethyl)-4-methoxyphenyl)imidazol-2-ylidene] has been synthesized and compared with its earlier methyl-substituted congener IPr* [N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene]. IPr*OMe was successfully bound to palladium, and the catalytic activity of the resulting complex [Pd(IPr*OMe)(acac)Cl] was investigated in Buchwald-Hartwig arylamination. Catalytic activity was compared to that of [Pd(IPr*)(acac)Cl].