14164-69-3Relevant academic research and scientific papers
Investigations on the Formation of 4-Aminobicyclo[2.2.2]octanones
Seebacher, Werner,Kroepfl, Dietmar,Belaj, Ferdinand,Saf, Robert,Huefner, Antje,Weis, Robert
, p. 676 - 688 (2007/10/03)
Benzylidene acetone reacts with thiocyanates derived from secondary amines in a one-pot reaction to give 4-aminobicyclo[2.2.2]octan-2-ones. The reaction mixture was investigated for the presence of possible intermediates using GC-MS. These intermediates -
Cyclodimerizations of Alkyl Styryl Ketones and Their Silyl Enol Ethers by Use of Iron Carbonyls
Ueda, Tatsuo,Otsuji, Yoshio
, p. 1635 - 1638 (2007/10/02)
The reaction of alkyl styryl ketones with Fe3(CO)12 gives 3-acyl-4,5-diphenylcyclohexanones in a manner of cyclodimerization. (η4-Enone)Fe(CO)3 complexes serve as catalyst for this reaction.Silyl enol ethers of the same ketones afford 4-a
