1416586-84-9

Basic information

• Product Name: [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc(H)(N(2,6-ⁱPr₂C₆H₃)(SiH₂Ph))]
• Synonyms: [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc(H)(N(2,6-ⁱPr₂C₆H₃)(SiH₂Ph))]
• CAS NO: 1416586-84-9
• Molecular Weight: 656.966
• Mol File: 1416586-84-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc(H)(N(2,6-ⁱPr₂C₆H₃)(SiH₂Ph))](CAS DataBase Reference)
• NIST Chemistry Reference: [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc(H)(N(2,6-ⁱPr₂C₆H₃)(SiH₂Ph))](1416586-84-9)
• EPA Substance Registry System: [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc(H)(N(2,6-ⁱPr₂C₆H₃)(SiH₂Ph))](1416586-84-9)

Safety Data

• Hazardous Substances Data: 1416586-84-9(Hazardous Substances Data)

Upstream product

• 1239886-72-6 [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc=N(2,6-ⁱPr₂C₆H₃)(DMAP)] 
• 694-53-1 phenylsilane 

Downstream Products

• 1416586-88-3 N-benzyl-1-phenyl-N-propylsilanamine 
• 1416586-85-0 [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc(N(2,6-ⁱPr₂C₆H₃)(SiH₂Ph))(κ²(N,N′)-PhNCHNPh)] 
• 1239886-72-6 [[MeC(N(2,6-ⁱPr₂C₆H₃))CHC(Me)(NCH₂CH₂NMe)]Sc=N(2,6-ⁱPr₂C₆H₃)(DMAP)] 
• 694-53-1 phenylsilane 

Relevant articles and documents

Reversible addition of the Si-H bond of phenylsilane to the Sc=N bond of a scandium terminal imido complex

The facile and reversible addition of the Si-H bond of phenylsilane to the Sc=N bond of the scandium terminal imido complex [LSc=NDIPP(DMAP)] (1; L = [MeC(N(DIPP))CHC(Me)(NCH2CH2NMe)]-, DIPP = 2,6-iPr2C6H3) is reported. The reaction gives the scandium anilido hydride [LSc(H)(N(DIPP)(SiH2Ph))] (2), and a labeling experiment shows a rapid σ-bond metathesis between Sc-H of the formed scandium anilido hydride and Si-H of phenylsilane during the reaction. 2 was trapped by an insertion reaction with diphenylcarbodiimide, giving the stable scandium anilido amidinate [LSc(N(DIPP)(SiH 2Ph))(κ2(N,N′)-PhNCHNPh)] (3). Furthermore, the scandium terminal imido complex can efficiently catalyze the hydrosilylation of N-benzylidenepropan-1-amine. The reaction was completed within 2 h at 50 C with 5 mol % of catalyst loading and highly selectively produced the monoaminosilane.