141665-80-7Relevant academic research and scientific papers
POLYMER SUPPORTED SYNTHESIS OF 2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOPYRANOSYL ESTERS OF AROMATIC CARBOXYLIC ACIDS
Krishnamurty, H. G.,Dabholkar, Kavita,Maheshwari, Nitin
, p. 1323 - 1330 (2007/10/02)
Aromatic carboxylic acids bound to Amberlyst A-26 react with α-acetobromoglucose to form 2,3,4,6-tetra-O-acetyl-1-O-aroyl-β-D-glucopyranose derivatives in good yield.Glucosylation occurs satisfactory with carboxylic acids and nitrophenols (pKa 7-4), but not with phenols whose pKa values higher (pKa ca 10).Selective glucosylation at the carboxylic group is easily achieved in the case of phenolic acids.
