141693-21-2

Basic information

• Product Name: Ethanethione, 1,2-diphenyl-2-(phenylamino)-2-(phenylthio)-
• CAS NO: 141693-21-2
• Molecular Formula: C26H21NS2
• Molecular Weight: 411.591
• Mol File: 141693-21-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanethione, 1,2-diphenyl-2-(phenylamino)-2-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethione, 1,2-diphenyl-2-(phenylamino)-2-(phenylthio)-(141693-21-2)
• EPA Substance Registry System: Ethanethione, 1,2-diphenyl-2-(phenylamino)-2-(phenylthio)-(141693-21-2)

Safety Data

• Hazardous Substances Data: 141693-21-2(Hazardous Substances Data)

Upstream product

• 4198-95-2 α-phenylimino-deoxybenzoin 
• 108-98-5 thiophenol 
• 141693-20-1 1,2-Diphenyl-2-[(Z)-phenylimino]-ethanethione 
• 60118-15-2 2,4-bis(phenylthio)-1,3-dithia-2λ⁵,4λ⁵-diphosphetane 2,4-disulphide 

Relevant articles and documents

THE BEHAVIOUR OF α-DIKETONE MONO-, AND DI-IMINE SYSTEMS TOWARDS 2,4-BIS(PHENYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE (JAPANESE REAGENT, JR)

2,4-Bis(phenylthio)-1,3-dithia-2,4-diphosphetane-2,4-disulfide (Japanese reagent, JR, 4) reacts with benzil monoanils 1a-c, in boiling THF to give the respective 1,2-diphenyl-2-(phenylthio)-2--ethane-1-thiones 6a-c.Compound 6a was also prepared by the action of (P2S5)x on 1a followed by addition of thiophenol to the produced thione 5a.Benzil dianils 2a-c reacted with reagent 4 in dry toluene to yield the respective phenyl-(phenylthio)--methane 8a-c.Possible reaction mechanisms were considered and structures of the new products were supported by compatible analytical and spectroscopic evidences. Key words: Benzil mono-imine; di-imines; Japanese reagent; homolytic fission, radical mechanism..