141695-18-3Relevant academic research and scientific papers
Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis
Capperucci, Antonella,Degl'Innocenti, Alessandro,Dondoli, Paolo,Nocentini, Tiziano,Reginato, Gianna,Ricci, Alfredo
, p. 6267 - 6276 (2007/10/03)
Ethynyl silyl ketone 1 proved to be a very efficient Michael acceptor in carbocupration and metallocupration reactions. In particular, when using carbocuprates, a smooth entry to polyenals can be obtained, while, when using metallocuprates, silyl- and stannylpropenoyl silanes may be obtained, very powerful intermediates in organic synthesis.
3-Iodopropenoylsylane: a Further Step in the Chemistry of Unsaturated Acylsilanes
Degl'Innocenti, Alessandro,Capperucci, Antonella,Bartoletti, Laura,Mordini, Alessandro,Reginato, Gianna
, p. 2081 - 2082 (2007/10/02)
(E)-3-iodo propenoyltriphenylsilane 2 undergoes smooth coupling reactions with a variety of unsaturated organostannanes to afford polyunsaturated acylsilanes.
