1417175-87-1

Basic information

• Product Name: C₁₄H₂₀O
• Synonyms: C₁₄H₂₀O
• CAS NO: 1417175-87-1
• Molecular Weight: 204.312
• Mol File: 1417175-87-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₀O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₀O(1417175-87-1)
• EPA Substance Registry System: C₁₄H₂₀O(1417175-87-1)

Safety Data

• Hazardous Substances Data: 1417175-87-1(Hazardous Substances Data)

Upstream product

• 1417175-76-8 C₈H₁₅BO₂ 
• 93-53-8 (S)-2-phenyl-propionaldehyde 

Relevant articles and documents

Enantioselective syn and anti homocrotylation of aldehydes: Application to the formal synthesis of spongidepsin

Whereas crotylboration has been a useful method for synthesis of stereochemically complex products, we have shown that homocrotylboration can be achieved with cyclopropanated crotylation reagents, and that the stereoselectivity of the reaction can be predicted by analogous models. This paper presents a full account of this work, including the first examples of asymmetric anti homocrotylation. The scope of this reaction is demonstrated with highly enantioselective homocrotylation of both aliphatic and aromatic aldehydes, as well as double diastereoselection studies. An application of the synthesis of the marine natural product spongidepsin is presented, as well as streamlined syntheses of homocrotylation reagents.