1417538-03-4Relevant articles and documents
A new mild method for the C-acylation of ketone enolates. a convenient synthesis of β-keto-esters,-thionoesters, and-thioesters
Hale, Karl J.,Grabski, Milosz,Flasz, Jakub T.
, p. 370 - 373 (2013)
A new method for ketone enolate C-acylation is described which utilizes alkyl pentafluorophenylcarbonates, thiocarbonates, and thionocarbonates as the reactive acylating agents, and MgBr2·Et2O, DMAP, and i-Pr2NEt as the reagents for enolization. A wide range of ketones have been observed to undergo clean C-acylation via this protocol.