1418014-39-7Relevant academic research and scientific papers
Synthesis, crystal structure, and cytotoxic property of bis(5-chloro-2-nitrobenzoato)bis(2-piperidin-1-ylethylamine)disilver(I)
Wang, Nong
, p. 86 - 89 (2013)
5-Chloro-2-nitrobenzoic acid reacts with silver oxide and 2- piperidin-1-ylethylamine to give a centrosymmetric dinuclear silver(I) complex, [Ag2(C7H3ClNO4)(C7H 16N2)2]. The complex was characterized by elemental analysis and X-ray diffraction. The two Ag atoms are bridged by two 2-piperidin-1-ylethylamine ligands, generating a 10-membered chelate ring. The distance between the two Ag atoms is 2.948(2) A. Each Ag atom in the complex is three-coordinated by one primary amine and one ternary amine N atoms from two symmetry-related 2-piperidin-1-ylethylamine ligands, and by one carboxylateOatom of a 5-chloro-2-nitrobenzoate ligand, forming a distorted Y-shaped coordination. In the crystal structure, the molecules are linked through intermolecular N-H...Ohydrogen bonds, forming chains running along the a-axis. The complex shows effective cytotoxic property to both carcinoma and normal cells. Copyright Taylor & Francis Group, LLC 2013.
