14181-83-0Relevant academic research and scientific papers
An efficient synthesis of 2-isoxazolines from α-haloketone oximes and dimethyl sulfonium salts
Zhao, Sen,Wang, Hang,Sun, Shaofa,Guo, Haibing,Chen, Zhiyu,Wang, Jian,Wang, Lu,Liang, Steven,Wang, Gangqiang
supporting information, p. 382 - 385 (2019/01/04)
2-Isoxazolines were synthesized efficiently from a formal [4+1] cycloaddition of nitrosoalkenes and sulfur ylides, which were generated in situ from α-haloketone oximes and dimethyl sulfonium salts. This approach provides a new method to synthesize a rang
Sodium nitrite catalyzed aerobic oxidative deoximation under mild conditions
Zhang, Guofu,Wen, Xin,Wang, Yong,Mo, Weimin,Ding, Chengrong
supporting information; experimental part, p. 4665 - 4668 (2011/07/29)
A mild, simple process for the effective deoximation of a wide range of ketoximes and aldoximes has been developed, which utilizes available NaNO 2 as the catalyst and molecular oxygen as the green oxidant. Notably Amberlyst-15, which acts as the initiator of NaNO2, can be reused without regeneration. This environmentally benign protocol could provide a valuable synthetic method for practical applications.
Hetero-Diels-Alder reaction of [60]fullerene with nitrosoalkene
Yang, Hai-tao,Ruan, Xiao-Jiao,Miao, Chun-bao,Xi, Hai-tao,Jiang, Yan,Meng, Qi,Sun, Xiao-qiang
body text, p. 7337 - 7339 (2010/03/01)
A new type of stable C60-fused dihydrooxazine derivatives was successfully prepared by the hetero-Diels-Alder reaction of C60 with nitrosoalkene generated in situ by extrusion of HBr from the corresponding α-bromooxime.
Insulinomimetic vanadyl-hydroxythiazolethione complexes with VO(S 2O2) coordination mode: The correlation between the activity and Hammett's substituent constant
Katoh, Akira,Yamaguchi, Mika,Saito, Ryota,Adachi, Yusuke,Sakurai, Hiromu
, p. 1274 - 1275 (2007/10/03)
Four kinds of vanadyl-hydroxythiazolethione complexes with VO(S 2O2) coordination mode were newly synthesized, and demonstrated for the first time that the insulinomimetic activity apparently correlates to the Hammett's substituent c
