141810-56-2

Upstream product

• 1005-56-7 phenylcarbonochloridothioate 
• 498-07-7 levoglucosan 

Downstream Products

• 14241-58-8 (1R,3S,5S)-6,8-dioxabicyclo[3.2.1]octan-3-ol 
• 145351-59-3 [(1S,3S,5R)-(6,8-Dioxa-bicyclo[3.2.1]oct-3-yl)oxy]-diphenyl-silane 
• 145351-58-2 Thiocarbonic acid O-((1R,2S,3R,5R)-3-hydroxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl) ester O-phenyl ester 
• 145351-62-8 Thiocarbonic acid O-((1S,3S,4R,5R)-3-hydroxy-6,8-dioxa-bicyclo[3.2.1]oct-4-yl) ester O-phenyl ester 
• 132682-95-2 Methyl-3-O-benzoyl-α-D-erythro-hexopyranoside 
• 141810-57-3 Methyl-3-O-benzoyl-β-D-erythro-hexopyranoside 
• 146431-48-3 1,6-anhydro-3-O-benzoyl-2,4-dideoxy-β-D-threo-hexopyranoside 
• 145351-60-6 Thiocarbonic acid O-((1R,2R,3S,4R,5R)-4-phenoxythiocarbonyloxy-3-trimethylsilanyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl) ester O-phenyl ester 

Relevant academic research and scientific papers

An expeditious enantiospecific synthesis of a precursor of the lactonic portion of mevinic acids

A short, enantiospecific synthesis of the methylglycoside 5, a precursor of the lactonic moiety present in all mevinic acids and analogues, starting with 1,6-anhydro-D-glucose is described.

The invention of radical reactions. Part XXXI. Diphenylsilane: A reagent for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry

Various thionocarbonates and xanthates of alcohols and bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with diphenylphenylsilane in good yield.

Tris(trimethylsilyl)silane and diphenylsilane in the radical chain dideoxygenation of 1,6-anhydro-D-glucose: A comparative study

The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.