1418182-96-3Relevant articles and documents
Mono-and bimetallic zwitterionic chromium(0) and tungsten(0) allenyls
Giner, Elena A.,Santiago, Alicia,Gómez-Gallego, Mar,Ramírez De Arellano, Carmen,Poulten, Rebecca C.,Whittlesey, Michael K.,Sierra, Miguel A.
, p. 5450 - 5461 (2015/06/16)
A series of stable chiral (racemic), formally neutral, zwitterionic mono- and bimetallic M(CO)5[C(OEt)=C=CR(NHC)] (M = Cr, W) σ-allenyls are ready available by the addition of N-heterocyclic carbenes (NHCs) to Cr(0) and W(0) alkynyl Fischer car
Structure and photoreactivity of stable zwitterionic group 6 metal allenyls
Santiago, Alicia,Gómez-Gallego, Mar,De Arellano, Carmen Ramírez,Sierra, Miguel A.
supporting information, p. 1112 - 1114 (2013/03/13)
The synthesis and mechanistic study of the unprecedented reactivity of a series of zwitterionic η1-metal allenyls are reported.