1418308-65-2Relevant academic research and scientific papers
Distinctive meta-directing group effect for iridium-catalyzed 1,1-diarylalkene enantioselective hydrogenation
Bess, Elizabeth N.,Sigman, Matthew S.
supporting information, p. 646 - 649 (2013/04/10)
An iridium-catalyzed asymmetric hydrogenation of 1,1-diarylkenes is described. Employing a novel, modular phosphoramidite ligand, PhosPrOx, in this transformation affords biologically relevant 1,1-diarylmethine products in good enantiomeric ratios (96.5:3
