141860-75-5Relevant academic research and scientific papers
HIGH YIELD PREPARATION OF 2,3,3-TRICHLORINATED TETRAHYDROPYRAN WITH AN EXCESS OF REFLUXING SULFURYL CHLORIDE IN THE DARK
Buyck, Laurent de
, p. 303 - 306 (2007/10/02)
The chlorination of tetrahydropyran with an excess of refluxing sulfuryl chloride in the dark provided 2,3,3-trichlorotetrahydropyran in 94percent isolated yield, showing evidence for a very selective non-homolytic mechansims, probably involving hydride abstraction as the first step.
