1418645-60-9

Basic information

• Product Name: C₄₁H₃₆N₂O*C₁₁H₁₅NO
• CAS NO: 1418645-60-9
• Molecular Weight: 749.996
• Mol File: 1418645-60-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₁H₃₆N₂O*C₁₁H₁₅NO(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₁H₃₆N₂O*C₁₁H₁₅NO(1418645-60-9)
• EPA Substance Registry System: C₄₁H₃₆N₂O*C₁₁H₁₅NO(1418645-60-9)

Safety Data

• Hazardous Substances Data: 1418645-60-9(Hazardous Substances Data)

Upstream product

• 54394-78-4 2-methylbutanoic acid anilide 
• 1418645-36-9 N,N'-ditrityl-(S)-2-aminopropanamide 
• 76-84-6 triphenylmethyl alcohol 
• 1418645-73-4 N-trityl-(S)-2-aminopropanamide 

Relevant articles and documents

Enantioselective inclusion of amide guests into a chiral N,N′-ditrityl amino amide host to compensate the loss of hydrogen bonds broken by installation of trityl groups

A new crystalline N,N′-ditrityl amino amide host included several amide guests in the host cavity to form inclusion crystals. Although the installation of trityl groups into (S)-2-aminopropanamide broke its inherent hydrogen bonds of amide groups, inclusion of guest amides compensated the loss of hydrogen bonds. X-ray crystallography showed that these inclusion cavities and host-guest interactions such as hydrogen bonds, van der Waals interaction, and CH?O interactions play important roles for highly enantioselective inclusion. The enantiomeric inclusion was 67% ee (S-form) for N-phenyl 2-methylbutanamide, 82% ee (S-form) for N-phenyl 2-chlorobutanamide, and 83% ee (S-form) for N-phenyl 2-bromobutanamide.