14190-40-0

Basic information

• Product Name: o-Fluorophenylthiocarbamoyl cyanide
• Synonyms: 1-Cyano-N-(2-fluorophenyl)thioformamide;o-Fluorophenylthiocarbamoyl cyanide
• CAS NO: 14190-40-0
• Molecular Formula: C₈H₅FN₂S
• Molecular Weight: 0
• Mol File: 14190-40-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: o-Fluorophenylthiocarbamoyl cyanide(CAS DataBase Reference)
• NIST Chemistry Reference: o-Fluorophenylthiocarbamoyl cyanide(14190-40-0)
• EPA Substance Registry System: o-Fluorophenylthiocarbamoyl cyanide(14190-40-0)

Safety Data

• Hazardous Substances Data: 14190-40-0(Hazardous Substances Data)

Relevant articles and documents

Some chemistry of 4,5-dichloro-1,2,3-dithiazolium chloride and its derivatives

4,5-Dichloro-1,2,3-dithiazolium chloride 1 reacts with fluoroanilines (see Table 1) to give the iminodithiazoles 5 in very high yield.Thermolysis of the latter gave the corresponding 2-cyanobenzothiazoles 6 together, in some cases, with the cyanoimidoyl chlorides 7.This reaction sequence provides modest yields of 2-cyanobenzothiazoles from the corresponding aniline, in two steps.Treatment of the iminodithiazoles with m-chloroperbenzoic acid in dichloromethane at or below room temperature opened the heterocyclic ring to give the N-arylcyanothioformamides (e.g. 8 --> 10), except for the p-nitrophenyl compound which gave p-nitrophenyl isothiocyanate 14 in high yield.