14192-97-3

Basic information

• Product Name: 2-Pyridinamine, N-phenyl-N-2-pyridinyl-
• Synonyms: 2-Pyridinamine,N-phenyl-N-2-pyridinyl
• CAS NO: 14192-97-3
• Molecular Formula: C16H13N3
• Molecular Weight: 247.299
• Mol File: 14192-97-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-Pyridinamine, N-phenyl-N-2-pyridinyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyridinamine, N-phenyl-N-2-pyridinyl-(14192-97-3)
• EPA Substance Registry System: 2-Pyridinamine, N-phenyl-N-2-pyridinyl-(14192-97-3)

Safety Data

• Hazardous Substances Data: 14192-97-3(Hazardous Substances Data)

Upstream product

• 109-04-6 2-bromo-pyridine 
• 62-53-3 aniline 
• 109-09-1 2-chloropyridine 
• 6631-37-4 2-(phenylamino)pyridine 
• 108-86-1 bromobenzene 
• 1202-34-2 di(pyridin-2-yl)amine 
• 591-50-4 iodobenzene 

Downstream Products

• 1262533-53-8 [Cu(N-phenyl-N,N-bis(2-pyridyl)amine)(Cl)(μ-Cl)]2 
• 1262533-75-4 [Cu(N-phenyl-N,N-bis(2-pyridyl)amine)(η2-styrene)][BF4]*(ethanol) 

Relevant articles and documents

A new reaction of N-aryl-2-pyrimidinamines with triphosgene

A new reaction of N-aryl-2-pyrimidinamines with triphosgene to afford N-aryl-N-(2-pyrimidinyl)-2-pyrimidinamine is described.

Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes

A highly efficient solvent-free protocol for the Buchwald-Hartwig (hetero)arylation of anilines, diarylamines, and dialkylamines mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp = 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene; cinn = cinnamyl, 3-phenylallyl] was developed. The catalytic protocol was efficient for the coupling of amines and (hetero)aryl chlorides and bromides bearing donor, acceptor, and bulky substituents.

NUCLEOPHILIC HETEROCYCLIC CARBENE DERIVATIVES OF PD(ACAC)2 FOR CROSS-COUPLING REACTIONS

Embodiments in accordance with the present invention provide for a palladium complex characterized by the general Formula (I): where A is a bidentate monoanionic ligand, NHC is a nucleophilic heterocyclic carbene, and Z is an anionic ligand. Such palladium complexes are useful in initiating cross-coupling reactions.