141989-40-4

Basic information

• Product Name: 2-(2-furyl)-1-methyl-1H-phenanthro[9,10-d]imidazole
• Synonyms: 2-(2-furyl)-1-methyl-1H-phenanthro[9,10-d]imidazole
• CAS NO: 141989-40-4
• Molecular Formula: C₂₀H₁₄N₂O
• Molecular Weight: 298.33796
• Mol File: 141989-40-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(2-furyl)-1-methyl-1H-phenanthro[9,10-d]imidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-furyl)-1-methyl-1H-phenanthro[9,10-d]imidazole(141989-40-4)
• EPA Substance Registry System: 2-(2-furyl)-1-methyl-1H-phenanthro[9,10-d]imidazole(141989-40-4)

Safety Data

• Hazardous Substances Data: 141989-40-4(Hazardous Substances Data)

Upstream product

• 36097-72-0 2-(furan-2'-yl)-1H-phenanthro[9,10-d]imidazole 
• 74-88-4 methyl iodide 
• 84-11-7 9,10-phenanthrenequinone 
• 98-01-1 furfural 

Downstream Products

• 342384-69-4 1-methyl-2-(5-phenyl-furan-2-yl)-1H-phenanthro[9,10-d]imidazole 

Relevant articles and documents

Synthesis and properties of 2-(2-furyl)- and 2-(2-thienyl)-1-methylphenanthro[9,10-d]imidazoles

Condensation of 9,10-phenanthrenequinone with 2-furaldehyde and 2-thiophenecarbaldehyde in glacial acetic acid in the presence of ammonium acetate gave 2-(2-furyl)- and 2-(2-thienyl)phenanthro[9,10-d]imidazoles which were converted into the corresponding 1-methyl derivatives. The furan and thiophene rings in the products lose their acidophobic properties. Depending on the conditions, electrophilic substitution reactions in 2-(2-furyl)- and 2-(2-thienyl)phenanthro[9,10-d]imidazoles occur both at the furan (thiophene) and phenanthrene moieties.

INVESTIGATIONS OF 2-SUBSTITUTED IMIDAZOLES. 2. SYNTHESIS AND ELECTROPHILIC SUBSTITUTION OF 1-METHYL-2-(THIENYL-2)IMIDAZOLE. A CONVENIENT METHOD OF METHYLATION OF 2-R-IMIDAZOLES

We have synthesized 2-(thienyl-2)imidazole and its N-methyl derivative.The latter product was obtained by nitration, bromination, acylation, and formylation, occurring as a rule on the thiophene ring.A general method for methylating 2-R-imidazoles with methyl iodide KOH-dimethoxy ethane is proposed.