141990-23-0Relevant academic research and scientific papers
A method for the syntheses of Enopyranosides
Khan, Khalid M.,Perveen, Shahnaz,Al-Qawasmeh, Raed A.S,Shekhani, Mohammed S.,Shah, Syed T. Ali,Voelter, Wolfgang
experimental part, p. 191 - 196 (2010/04/23)
Sodium hydride (NaH) in hexamethylphosphoric triamide (HMPA) has been introduced as an economical and efficient reagent towards the creation of 1, 2- or 5, 6-enopyranosides from the corresponding halogenated or tosylated pyranosides. NaH/HMPA has several advantages compared to NaH/DMF: elimination products are produced in high yields even from sterically-hindered halides as well as tosylates. 2009 Bentham Science Publishers Ltd.
