1420041-75-3Relevant academic research and scientific papers
Synthesis of fluorinated amphoteric organoborons: Via iodofluorination of alkynyl and alkenyl MIDA boronates
Fan, Wen-Xin,Li, Ji-Lin,Lv, Wen-Xin,Yang, Ling,Li, Qingjiang,Wang, Honggen
, p. 82 - 85 (2019/12/25)
The iodofluorination of alkynyl and alkenyl MIDA (N-methyliminodiacetyl) boronates led to the synthesis of two types of fluorinated organoborons bearing a valuable C-I bond. The B(MIDA) moiety confers exclusive regioselectivity to the reaction, and the products were formed in generally good yields. Preliminary utility of the products was demonstrated.
Silver-assisted difunctionalization of terminal alkynes: Highly regio- and stereoselective synthesis of bromofluoroalkenes
Li, Yibiao,Liu, Xiaohang,Ma, Deyun,Liu, Bifu,Jiang, Huanfeng
, p. 2683 - 2688 (2013/01/15)
The difunctionalization of terminal alk- ACHTUNGTRENUNGynes was achieved with silver fluoride (AgF) and N-bromosuccinimide (NBS) as halogen sources. The presence of the halide moiety greatly enhances the reactivity of the vinyl fluoride compounds that can probably can be transformed into various products that are difficult or even impossible to obtain via direct fluorination. Meanwhile, the monofluoro alkenes were facilely synthesized via a highly chemo- and regioselective fluorination of electron-deficient C-C triple bonds using AgF as fluorinating reagent in good yields
