142025-08-9Relevant academic research and scientific papers
Improved procedure for the hydrotelluration of alkynes
Zeni, Gilson,Formiga, Henrique B.,Comasseto, Jo?o V.
, p. 1311 - 1313 (2007/10/03)
Z-Vinylic tellurides were prepared by hydrotelluration of alkynes with lithium butyl tellurolate generated by reaction of n-butyllithium with elemental tellurium. (C) 2000 Elsevier Science Ltd.
Tellurium in organic synthesis. Preparation of Z-vinylic cuprates from Z-vinylic tellurides and their reaction with enones and epoxides
Tucci, Fabio C.,Chieffi, Andre,Comasseto, Joao V.,Marino, Joseph P.
, p. 4975 - 4989 (2007/10/03)
Z-Vinylic tellurides, obtained with 100% stereoselectivity by the hydrotelluration of acetylenes, are easily transformed into Z-vinylic higher order cyanocuprates by reaction with preformed Me2-Cu(CN)Li2, W-Bu2Cu(CN)Lisub
Iodocyclization of (Z)-1-(butyltelluro)-1,4-diorganylbut-1-en-3-ynes. Synthesis and reactions of 3-iodotellurophenes
Dabdoub, Miguel J.,Dabdoub, Va?nia B.,Pereira, Marco A.,Zukerman-Schpector, Julio
, p. 9503 - 9511 (2007/10/03)
The iodocyclization of (Z)-tellurobutenynes 5a-g by reaction with I2/petroleum ether was studied in detail. 3-Iodotellurophenes 7a-f were formed, and optimum conditions to obtain these compounds in high yields were established. The reaction inv
Synthesis of (E)-1,4-bis(organyl) but-1-en-3-ynes by lithium-tellurium exchange reaction on (Z)-1-butyltelluro-1,4-bis(organyl) but-1-en-3-ynes
Dabdoub,Dabdoub,Comasseto
, p. 2261 - 2264 (2007/10/02)
1,4-bis(organyl)-1,3-butadiynes react with dibutyl ditelluride and sodium borohydride in ethanol under reflux to give (Z)-1-butyltelluro-1,4-bis(organyl) but-1-en-3-ynes, which by treatment with butyllithium followed by water give (E)-1,4-bis(organyl) but
