142031-46-7Relevant articles and documents
Titanium-Catalyzed Hydroaminoalkylation of Ethylene
Rosien, Michael,T?ben, Iris,Schmidtmann, Marc,Beckhaus, Rüdiger,Doye, Sven
supporting information, p. 2138 - 2142 (2020/02/05)
The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti?C bond of a titanaaziridine is reported.
Microwave-promoted selective mono-n-alkylation of anilines with tertiary amines by heterogeneous catalysis
Lubinu, M. Caterina,De Luca, Lidia,Giacomelli, Giampaolo,Porcheddu, Andrea
supporting information; experimental part, p. 82 - 85 (2011/03/21)
A palladium-catalyzed N-alkylation of anilines with tertiary amines that occurs under heterogeneous transfer-hydrogenation conditions has been developed (see scheme). This protocol of transamination, which uses a relatively cheap and easily recyclable heterogeneous catalyst, can be efficiently applied to different substrates and is suitable for large-scale preparations.
Copper catalyzed coupling of aryl chlorides, bromides and iodides with amines and amides
Xu, Hanhui,Wolf, Christian
supporting information; experimental part, p. 1715 - 1717 (2009/08/08)
A copper(i) catalyzed procedure for carbon-nitrogen bond formation utilizing aryl halides and either amines, including amino acids and diphenylamine, or aliphatic and aromatic amides is described. The Royal Society of Chemistry.
