1420472-32-7

Basic information

• Product Name: (E)-1-(4-chlorophenyl)ethanone O-acetyl oxime
• Synonyms: (E)-1-(4-chlorophenyl)ethanone O-acetyl oxime
• CAS NO: 1420472-32-7
• Molecular Weight: 211.648
• Mol File: 1420472-32-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(4-chlorophenyl)ethanone O-acetyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(4-chlorophenyl)ethanone O-acetyl oxime(1420472-32-7)
• EPA Substance Registry System: (E)-1-(4-chlorophenyl)ethanone O-acetyl oxime(1420472-32-7)

Safety Data

• Hazardous Substances Data: 1420472-32-7(Hazardous Substances Data)

Upstream product

• 99-91-2 para-chloroacetophenone 
• 1956-39-4 4-chloroacetophenone oxime 
• 108-24-7 acetic anhydride 

Downstream Products

• 906782-83-0 2-(4-chlorophenyl)-7-methyl-1H-indole 
• 1402452-24-7 6-chloro-1-methyl-3-phenylisoquinoline 
• 1198575-42-6 1-methyl-3,4-diphenyl-6-chloro-isoquinoline 
• 92520-15-5 (R)-N-[1-(4-chlorophenyl)ethyl]acetamide 
• 186296-21-9 (S)-N-[1-(4-chlorophenyl)ethyl]acetamide 

Relevant articles and documents

Polysubstituted Indole Synthesis via Palladium/Norbornene Cooperative Catalysis of Oxime Esters

Polysubstituted indoles are prevalent in pharmaceuticals, agrochemicals, and organic materials. Presented herein is the fact that polyfunctionalized indoles can be efficiently constructed from easily accessible oxime esters and aryl iodides, involving a palladium/norbornene synergistic synthesis. The reaction is enabled by a unique class of electrophiles in palladium/norbornene cooperative catalysis, which are oxime esters derived from simple ketone. The broad substrate scope and high functional group tolerance could make this method attractive for the synthesis of polysubstituted indoles.