142048-19-9Relevant articles and documents
Synthesis and diastereoselective complexation of enantiopure sulfinyl dienes: The preparation of sulfinyl iron(0) dienes
Paley, Robert S.,De Dios, Alfonso,Estroff, Lara A.,Lafontaine, Jennifer A.,Montero, Carlos,McCulley, David J.,Rubio, M. Belen,Ventura, Maria Paz,Weers, Heather L.,De la Pradilla, Roberto Fernandez,Castro, Sonia,Dorado, Rocio,Morente, Miguel
, p. 6326 - 6343 (2007/10/03)
The preparation of a diverse array of enantiomerically pure 1- and 2- sulfinyl dienes has been achieved via Stille coupling of halovinyl sulfoxides and vinyl stannanes, hydrogenation of 1-sulfinyl-1-en-3-ynes, or vinylcupration of 1-sulfinyl alkynes. Form
Stereocontrolled Synthesis of Enantiomerically Pure 2-Dienyl Sulfoxides via Palladium-Catalyzed Coupling Reactions
Paley, Robert S.,Weers, Heather L.,Fernandez, Paloma
, p. 3605 - 3608 (2007/10/02)
Enantiopure 2-sulfinyl dienes can be prepared via regio- and stereoselective hydrostannylation of alkynylsulfoxides; after conversion to the corresponding vinyliodides these substrates may be coupled with vinylstannanes via Stille methodology in the prese
An easy synthesis of chiral sulfinyl allylic bromides and their use in the preparation of (R)(S)- and (S)(S)-2-p-tolylsulfinyl-1,3-alkadienes
Bonfand,Gosselin,Maignan
, p. 1667 - 1676 (2007/10/02)
Condensation of (R)-vinyl-o-tolylsulfoxide anion on carbonyl compounds led directly to chiral allylic sulfinylalcohols 1. By treatment with NBS/Me2S, these alcohols 1 were converted into the rearranged primary allylic bromides 2 via SN2/s
First syntheses of chiral 2-sulfinylbutadienes
Bonfand,Gosselin,Maignan
, p. 2347 - 2348 (2007/10/02)
The title compounds were readily prepared respectively from (S)-3-p-tolylsulfinylbut-3-en-2-ol 3 and (S)-3-p-tolylsulfinylbut-3-en-2-one 4.
