142054-94-2Relevant academic research and scientific papers
Intermolecular reactions of N-alkoxycarbonyliminium ions with propargyltrimethylsilane; oxazinone versus allene formation
Esch,Hiemstra,Speckamp
, p. 3445 - 3462 (2007/10/02)
Intermolecular reactions of N-alkoxycarbonyliminium ions with propargyltrimethylsilane mainly lead to 6-(trimethylsilyl)methyl-3,4-dihydro-2H-1,3-oxazinones, formed by intramolecular trapping of a stabilized β-sily vinylic cation. α-Allenyl carbamates are obtained as minor products. The oxazinone/allene ratio is dependent on the nature of the Lewis acid and the solvent used.
OXAZINONE VERSUS ALLENE FORMATION IN THE REACTION OF N-ALKOXYCARBONYLIMINIUM IONS WITH PROPARGYLTRIMETHYLSILANE
Esch, Peter M.,Hiemstra, Henk,Speckamp, W. Nico
, p. 367 - 370 (2007/10/02)
Reaction of N-alkoxycarbonyliminium ions with propargyltrimethylsilane, promoted by Lewis acid, yield in most cases mixtures of allenes G and oxazinones H.
