142072-44-4Relevant academic research and scientific papers
Studies on 1-Trimethylsilyl-2,4,6-triethylborazine and Related Species
Niedenzu, Kurt,Serwatowska, Joanne,Serwatowski, Janusz
, p. 713 - 717 (2007/10/02)
Key Words: Boron-Nitrogen Compounds, Borazines, Unsymmetrically Substituted Borazines, Polyborazines The unsymmetrically substituted borazine (C6H5)3B3N3H2 has been obtained from the reaction of C6H5BCl2 with HN2, and an improved synthesis of (C2H5)3B3N3H2 has been developed.The reaction of the latter with an excess of BCl3 proceeds with the ultimate formation of Cl3B3N3H2, whereas the reaction with one molar equivalent of BBr3 leads to the formation of Br(C2H5)2B3N3H2a diborazinyl and additional products.C6H5BBr2 reacts with N3 to give the aminoborane 2NBBr(C6H5), but C6H5BCl2 does not undergo a reaction under analogous conditions.
