142075-75-0

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 103959-51-9 (2S,3S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-2-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-pentanethioic acid S-tert-butyl ester 
• 102614-13-1 2-phenyl-4(S)-<2-((2-methyl-2-propyl)thio)-2-oxoethyl>-2-oxazoline 
• 89922-82-7 3-(tert-butyldimethylsilanyloxy)propionaldehyde 

Downstream Products

• 142075-79-4 (S)-4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-4,5-dihydro-oxazole 
• 142075-81-8 (S)-4-[(1S,2S)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-1-vinyl-butyl]-2-phenyl-4,5-dihydro-oxazole 
• 142075-64-7 4-[(1S,2S)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-1-vinyl-butyl]-2-phenyl-oxazole 
• 142075-68-1 C₂₇H₄₅NO₅Si₂ 
• 142075-66-9 [(4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-5-(2-phenyl-oxazol-4-yl)-hept-6-enyl]-phosphonic acid dimethyl ester 
• 142075-72-7 C₂₄H₃₈NO₈PSi 
• 142075-63-6 (3R,4S)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(2-phenyl-oxazol-4-yl)-1-phenylsulfanyl-hexan-2-ol 
• 142075-62-5 4-[(1S,2S)-1-[(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-phenyl-oxazole 
• 142075-71-6 C₃₃H₅₁NO₆SSi₂ 
• 142075-69-2 C₃₄H₆₁NO₆Si₃ 
• 142075-80-7 (3R,4S)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-3-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-1-phenylsulfanyl-hexan-2-ol 

Relevant academic research and scientific papers

2-PHENYLOXAZOLINES AS CARBOXYLATE PRECURSORS - APPLICATION TO THE SYNTHESIS OF ASYMMETRIC BRANCHED-CHAIN STRUCTURES

A synthetic approach to the title compounds is presented that features the asymmetric elaboration of a chiral, non-racemic oxazoline followed by a two-step oxidative ring cleavage of the heterocycle to a triamide for further transformation.